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Photoluminescence of YVO4:Tm phosphor prepared by a polymerizable complex method

Identifieur interne : 001B20 ( Main/Exploration ); précédent : 001B19; suivant : 001B21

Photoluminescence of YVO4:Tm phosphor prepared by a polymerizable complex method

Auteurs : HONGWU ZHANGA [République populaire de Chine] ; XIAOYAN FU [République populaire de Chine] ; SHUYUN NIU [République populaire de Chine] ; GONGQUAN SUN [République populaire de Chine] ; QIN XIN [République populaire de Chine]

Source :

RBID : Pascal:04-0578523

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Abstract

This paper reports the photoluminescence (PL) properties of nanocrystalline YVO4: Tm phosphor synthesized by the polymerizable complex method based on the Pechini-type reaction. The powder was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), absorption spectroscopy and PL. The results of XRD and TEM show that, high-quality nanopowders with controlled morphology and microstructure were prepared at a relatively low temperature about 700 °C. Upon ultra violet excitation the vanadate host transferred energy to thulium ions efficiently and strong blue emission (475 nm) assigned to 1G43H6 transmission is observed. By analyzing excitation and emission spectra of thulium doped yttrium vanadate, we deduced the mechanism of the energy transfer between vanadate host and thulium ions.


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Le document en format XML

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<title xml:lang="en" level="a">Photoluminescence of YVO
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:Tm phosphor prepared by a polymerizable complex method</title>
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<title xml:lang="en" level="a">Photoluminescence of YVO
<sub>4</sub>
:Tm phosphor prepared by a polymerizable complex method</title>
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<name sortKey="Hongwu Zhanga" sort="Hongwu Zhanga" uniqKey="Hongwu Zhanga" last="Hongwu Zhanga">HONGWU ZHANGA</name>
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<sZ>1 aut.</sZ>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Absorption spectra</term>
<term>Doping</term>
<term>Energy transfer</term>
<term>Excitation spectrum</term>
<term>Experimental study</term>
<term>Impurities</term>
<term>Microstructure</term>
<term>Nanocrystal</term>
<term>Phosphors</term>
<term>Photoluminescence</term>
<term>Thulium additions</term>
<term>Transmission electron microscopy</term>
<term>XRD</term>
<term>Yttrium Vanadates</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Photoluminescence</term>
<term>Diffraction RX</term>
<term>Microscopie électronique transmission</term>
<term>Spectre absorption</term>
<term>Microstructure</term>
<term>Spectre excitation</term>
<term>Dopage</term>
<term>Impureté</term>
<term>Transfert énergie</term>
<term>Addition thulium</term>
<term>Matériau luminescent</term>
<term>Nanocristal</term>
<term>Yttrium Vanadate</term>
<term>Etude expérimentale</term>
<term>YVO4:Tm</term>
<term>O V Y</term>
<term>7867B</term>
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<term>Dopage</term>
</keywords>
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<front>
<div type="abstract" xml:lang="en">This paper reports the photoluminescence (PL) properties of nanocrystalline YVO
<sub>4</sub>
: Tm phosphor synthesized by the polymerizable complex method based on the Pechini-type reaction. The powder was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), absorption spectroscopy and PL. The results of XRD and TEM show that, high-quality nanopowders with controlled morphology and microstructure were prepared at a relatively low temperature about 700 °C. Upon ultra violet excitation the vanadate host transferred energy to thulium ions efficiently and strong blue emission (475 nm) assigned to
<sup>1</sup>
G
<sub>4</sub>
<sup>3</sup>
H
<sub>6</sub>
transmission is observed. By analyzing excitation and emission spectra of thulium doped yttrium vanadate, we deduced the mechanism of the energy transfer between vanadate host and thulium ions.</div>
</front>
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